Historical Dates from an Australian Perspective.
28th June 1914 - Assassination of Archduke Franz Ferdinand and wife, heir to Austro-Hungarian Empire.
28th July 1914 - Is accepted as the Start of World War One when Austro-Hungarian Empire declared war on Serbia.
3rd August 1914 Monday - Germany declares war on France
3rd August 1914 Monday - Following Canada and New Zealand, PM Cook announces that Australia offers a 20000 man force to the Motherland.
4th August 1914 Tuesday - Germany enters Belgium, Britain responds by declaring war on Germany.
5th August 1914 Wednesday - The then Governor General, Sir Ronald Munro Ferguson, received the cable that Britain had declared war on Germany at midday local time on 5 August. Prime Minister Cook then advised the people that Australia was at war with Germany. Australia did not have to 'declare war' as back then it had no constitutional right. Suffice to say, if 'Britain was at war', that meant Australia was at war.
The first hostile shot of the war (British and Dominions) occurred in Australia when the Victorian Fort Nepeanfire fired at the German merchant ship Pfalz trying to leave Port Phillip Bay.
10th August 1914 - AIF recruitment commences.
19th August 1914 - Australian Forces depart to capture German interests in New Guinea and Islands.
1st November 1914 - Convoy first AIF Leaves.
So It Begins, at the start of Great War Australia pledged 20000 men by the end of WW1, on the 11th November 1918, 330000 odd Australians had been sent to the front.
information sourced from Australian War Books